ABC News March 5, 2022

Former Ukrainian President Victor Yushchenko says he doesn't think Putin will resort to nuclear option

WATCH: Is Putin's invasion of Ukraine backfiring?

Though threatened by the Kremlin for decades, for former Ukrainian President Victor Yushchenko, the Russian invasion of his country, he says, is a tragedy that Ukrainians didn't envision becoming reality.

The 68-year-old told ABC's "Nightline" the situation has united his people in a way that caught Russian forces off guard.

"Russia has never in its history encountered such determination, such a high democratic spirit and spirit for freedom," Yushchenko told ABC News in a video interview from an undisclosed location in Ukraine. "In terms of spirit, [of] understand[ing], a totalitarian Russia cannot defeat Ukraine."

Former Ukrainian President Victor Yushchenko speaks with ABC News about the Russian invasion of his country.

Yushchenko, who served as the country's president from 2005 to 2010, said Ukraine has developed a democracy for the last 20 years despite internal bickering.

He called Russia's invasion the "biggest onslaught on our territory" since the Mongols tried to invade Ukraine in the 13th century, however, he said that he did not believe that Russian President Vladimir Putin would go to the extremes to try to take over his country.

"I don't think that we'll find anyone in the Russian military -- even in the disorganized military it is right now -- or any two officers who will be ready to turn the key and launch nuclear rockets towards Ukraine, or somewhere else," Yushchenko said.

Yushchenko said the Russian occupation of the Chernobyl and Zaporizhzhia nuclear power plants, is Putin's idea "that he's a 'macho man' and that he's so strong he can exploit nuclear threat to achieve his goals."

MORE: Fighting around Ukraine's nuclear plants raises global concerns

"Putin is in an absolute, extreme isolation and that is why, every day, his reputation as the Russian president declines and his political beliefs, including nuclear inclinations, are devaluing fast," he said.

Aris Messinis/AFP via Getty Images
Smoke rises from a bombed warehouse in the town of Stoyanka, west of Kyiv, on March 4, 2022.

By comparison, Ukrainian President Volodymyr Zelenskyy has worked hard to consolidate the Ukrainian nation, Yushchenko said.

"He’s doing very important work. It's possible,” he added, “that we've not been this united in 30 years. Tragedy and pain can unite."

Former Ukrainian President Victor Yushchenko speaks with ABC News about the Russian invasion of his country.

Zelenskyy has continually released televised updates as Russian forces continue to launch missile attacks and advance on the ground into the country. Zelenskyy has said he is Russia’s number one target in this war, his family, the second.

Yushchenko is no stranger to threats against his own life. He survived a dioxin poisoning in 2004 when he ran against a Kremlin-favored candidate for the presidency.

Yushchenko's face was memorably heavily disfigured for years and some Ukrainian officials alleged that the Russian government was involved. The Kremlin has never officially responded to those allegations.

AFP via Getty Images
Pro-West opposition leader Viktor Yushchenko gestures under his own portrait during a press conference in Kyiv, Ukraine, Dec. 10, 2004. Ukraine's opposition leader and presidential candidate Viktor Yushchenko reiterated here today his assertion that the disfiguration of his face was the result of an attempt to kill him by poisoning.

Yushchenko said his country is appreciative of the steps taken by the U.S. and Western allies to help the Ukrainian people, including sanctions and aid, but he reiterated calls for a no-fly zone.

The former president said "the Achilles' heel of the Ukrainian defense" is strategic Russian airstrikes.

"When we're talking about what Ukrainian soldiers want to have on the war field, any soldier's first sentence would be 'close airspace over Ukraine,'" he said.

ABC News' Mary Marsh and Karin Weinberg contributed to this report.