Speaking just hours after Ukrainian President Volodymyr Zelenskyy called on him to be a "leader for peace," President Joe Biden on Wednesday thanked Zelenskyy for his "passionate message" and detailed how much military aid the U.S. is already providing -- or will provide -- to Ukraine.
Biden called Zelenskyy's speech "convincing and significant" and said he listened to him from the White House private residence.
"He speaks for people who have shown remarkable courage and strength in the face of brutal aggression -- courage and strength that’s inspired not only Ukrainians but the entire world," Biden said. "Putin is inflicting appalling, appalling devastation and harm on Ukraine -- bombing apartment buildings, maternity wards, hospitals. I mean, it’s -- it's God awful."
He did not directly address Zelenskyy's emotional and direct appeal to lawmakers on Wednesday for the U.S. to back a no-fly zone the administration has repeatedly rejected -- but announced an additional $800 million in military assistance as part of the $13.6 billion aid package for Ukraine contained in the government spending bill Biden signed into law Tuesday, which includes weapons the Ukrainians have been requesting, such as anti-armor and anti-air systems.
Ahead of signing an action to approve the $800 million in additional security support, Biden said the U.S. is "fully committed" to getting more weapons to Ukraine.
"What’s at stake here are the principles that the United States and the United Nations and across the world stand for. It's about freedom. It’s about the right of people to determine their own future. It's about making sure Ukraine never, will never be a victory for Putin no matter what advances he makes on the battlefield," he said.
MORE: Ukraine's Zelenskyy invokes Pearl Harbor, 9/11, calls out Biden in plea to Congress for more US help"The American people are answering President Zelenskyy's call for more help, more weapons for Ukraine to defend itself, more tools to fight Russian aggression. And that’s what we’re doing," Biden said.
While not addressing Zelenskyy's request for a humanitarian no-fly zone, Biden said the new package will supply Ukraine with 9,000 anti-armor systems, 7,000 small arms, 800 Stinger anti-aircraft systems, 20 million rounds of ammunition, and 100 drones, "so they can continue to defend their space."
"At the request of President Zelenskyy, we have identified and are helping Ukraine acquire additional longer-range anti-aircraft systems and ammunitions for those systems," he said. "And this will include drones which demonstrates our commitment to sending our most cutting-edge systems to Ukraine for its defense."
"Now, I want to be honest with you. This could be a long and difficult battle, but the American people will be steadfast in our support of the people of Ukraine in the face of Putin’s immoral, unethical attacks on civilian populations," he added. "We are united in our abhorrence of Putin’s depraved onslaught, and we are going to continue to have their backs as they fight for freedom, their democracy, their very survival -- and we are going to give Ukraine the arms to fight and defend themselves through all the difficult days ahead."
Over the past week, the U.S. has contributed $1 billion in new assistance to Ukraine.
But White House press secretary Jen Psaki also reiterated Tuesday that the administration doesn't support Zelenskyy's no-fly zone request because the U.S. has to consider its own national security, and as Biden has repeatedly put it, does not want to enter "World War III."
"We have the responsibility to do here is to assess what the impact is on the United States and our own national security," she said.
While the U.S. has imposed a slate of economic and trade sanctions to isolate Putin, the Biden administration has also flatly rejected U.S. troops fighting Russian forces in Ukraine and any help delivering MiG-29 fighter jets that Poland wants to get to the Ukrainians.
MORE: Russia-Ukraine live updates: Russian forces 'struggling' with terrain: UK militaryEarlier Wednesday, to a packed auditorium of lawmakers and standing ovations, Zelenskyy seized the spotlight to push Biden to contribute more lethal aid, lawmakers to sanction more companies with ties to Russia, and said if the U.S. cannot agree to support a no-fly zone, then to give Ukraine S-300 systems and other similar weapons to defend its skies.
While the White House event allowed Biden to detail what the U.S. is doing in place of a no-fly zone, he was forced to respond to Zelenskyy's emotional appeal, in which he told Americans to remember Pearl Harbor and the 9/11 attacks when witnessing the terror in Ukraine and closed by calling out Biden by name, in English, to do more.
"It's not enough to be the leader of the nation. Today it takes to be the leader of the world," Zelensky said. "Being the leader of the world means to be the leader of peace. Peace in your country doesn't depend anymore only on you and your people. It depends on those next to you and those who are strong."
MORE: Biden, Congress get a Zelenskyy test: The NoteIn remarks on the Senate floor following Zelenskyy's address, Minority Leader Mitch McConnell criticized the Biden administration for what he's characterized as a sluggish response to the crisis in Ukraine and outlined three steps the administration should take to pick up the pace.
McConnell called on Biden to expand the scope of U.S. lethal aid to Ukraine to include more effective long-range air defense capabilities, to deploy more U.S. forces to reinforce NATO's eastern flank and use new authorities to harden the defenses of frontline allies, and finally, for Biden to go "beyond Brussels" on his trip next week and to visit Eastern flank, NATO allies like Poland, Romania and Lithuania.
"As the threat to Ukraine gathered whenever an opportunity to act has presented itself, the Biden administration has hesitated until the political pressure became overwhelming, or balked outright," McConnell said.
Although he made no direct mention of a no-fly zone, McConnell hit hard on the need to help Ukraine shore up its air defense, arguing the administration should quickly get Ukraine air defense systems "that we should have helped Ukraine get weeks ago."
MORE: Biden to head to Brussels next week for show of unity with NATO leadersBiden will travel to Brussels next Thursday to meet with NATO leaders in his first European visit since Russian President Vladimir Putin started invading Ukraine, the White House announced Tuesday, to meet "face-to-face" with his European counterparts to assess Russia's invasion of Ukraine.
ABC News' Allison Pecorin, Molly Nagle, Conor Finnegan, Luis Martinez and Justin Gomez contributed to this report.